BioDomus Immuno Plus

Limewash Product

TDS
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1 Identification of the Substance/Mixture & 0f the Company/Undertaking

1.1 Product identifier

Code     None
Product Name     BioDomus Immuno Plus

1.2 Relevant Identified Uses of the Substance or Mixture & Uses Advised Against

Intended Use     Sanitising Silicate Modified Emulsion Paint for Interior

1.3 Details of the Supplier of the Safety Data Sheet

  • Name     ROMA – Eco-Sustainable Building Technologies
  • Full Address     554 North Avenue NW, Suite B
  • District & Country Atlanta, GA 30318 | United States of America (USA)
  • 678-905-3700

1.4 Emergency Telephone Number

For Urgent Inquiries Refer To      Call 911 if you have a poison emergency.
Call the CDC if swallowed but person is alert 1-800-222-122

2 Hazards Identification

2.1 Classification of the Substance or Mixture

The product is classified as hazardous pursuant to the provisions set forth in Directives 67/548/EEC and 1999/45/EC and/or EC Regulation 1272/2008 (CLP) (and subsequent amendments and supplements). The product thus requires a safety data sheet that complies with the provisions of EC Regulation 1907/2006 and subsequent amendments.

Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.

  • Danger Symbols     Xi
  • R Phrases       52/53

The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.

2.2 Label Elements

Hazard labeling pursuant to Directives 67/548/EEC and 1999/45/EC and subsequent amendments and supplements.

  • S52/53     Harmful to Aquatic Organisms, May Cause Long-Term Adverse Effects in the Aquatic Environment
  • S2     Keep Out of the Reach Of Children.
  • S37     Wear Suitable Protective.
  • S46     If Swallowed, Seek Medical Advice Immediately and Show this Container or Label.

CONTAINS     2-OTTIL-2H-ISOTIAZOL-3-ONE

May produce an allergic reaction.

2.3 Other Hazards

Information not available.

3 Composition/Information on Ingredients

3.1 Substances

Information not relevant.

3.2 Mixtures

Identification Conc. % Class. 67/548/EEC Class. 1272/2008 (CLP)
CALCIUM HYDROXIDE
CAS     215-199-1 0.5 Xi R36/38 Eye Irrit. 2 H319, Skin Irrit. 2 H315
EC     215-199-1
INDEX     –
Reg. NO. 01-2119456888-17
CALCIUM HYDROXIDE
CAS     7761-88-8 0.025 – 0.10 C R34, N R50/53, O R 8 Ox. Liq. 2 H272, Skin Corr. 1B H314, Aquatic Acute 1 H400, 1 H410 Aquatic Chronic
EC     231-853-9
INDEX     047-001-00-2
Reg No     –

T+ = Very Toxic (T+), T = Toxic(T), Xn = Harmful (Xn), C = Corrosive (C), Xi = Irritant (Xi), O = Oxidizing (O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = Dangerous for the Environment (N)

The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet.

First Aid Measures

4.1 Description of First Aid Measures

No harm to the staff authorized to use has been reported. However, in case of contact, inhalation or ingestion, the following general measures provided for a first aid shall be taken.

  • Eyes & Skin     Wash with plenty of water; if the irritation persists, seek medical advice.
  • Inhalation     Remove to open air. If respiration is difficult, administer artificial respiration and seek medical advice.
  • Ingestion     Seek medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person.

4.2 Most Important Symptoms & Effects, Both Acute & Delayed

No episodes of damage to health ascribable to the product have been reported.

4.3 Indication of Any Immediate Medical Attention & Special Treatment Needed

Follow doctor’s orders.

5 Firefighting Measures

5.1 Extinguishing Media

SUITABLE EXTINGUISHING MEDIA

The extinction equipment should be of the conventional kind: Carbon Dioxide, Foam, Powder and Nebulized Water.

EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS

None in particular.

5.2 Special Hazards Arising From the Substance or Mixture

HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE
Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc.).

5.3 Advice for firefighters

GENERAL INFORMATION

Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations.

SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS

Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and antistatic), a depressurized mask with facemask covering the whole of the operator’s face or a self-respirator (self-protector) in the event of large quantities of fume.

6 Accidental Release Measures

6.1 Personal Precautions, Protective Equipment & Emergency Procedures

If there are no contraindications, spray powder with water to prevent the formation of dust. Use breathing equipment if powders are released into the air.

6.2 Environmental Precautions

The product must not penetrate the sewers, surface water, ground water and neighboring areas.

6.3 Methods & Material for Containment & Cleaning Up

Use mechanical tools to collect leaked product and eliminate the remainder using jets of water. Make sure the leakage site is well aired. Contaminated material should be disposed of in compliance with the provisions set forth in point 13.

6.4 Reference to Other Sections

Any information on personal protection and disposal is given in sections 8 and 13.

7 Handling & Storage

7.1 Precautions for Safe Handling

Store in closed, labeled containers.

7.2 Conditions for Safe Storage, Including Any Incompatibilities

Normal storage conditions without particular incompatibilities.

7.3 Specific End Use(s)

Information not available.

8 Exposure Controls/Personal Protection

8.1 Control Parameters

Name Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
CALCIUM HYDROXIDE TLV-ACGIH 10
TALC TLV-ACGIH 2
TITANIUM DIOXIDE TLV-ACGIH 10

8.2 Exposure Controls

As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration or bad air vent. If such operations do not make it possible to keep the concentration of the product below the permitted workplace exposure thresholds a suitable respiratory tract protection must be used. See product label for hazard details during use. Ask your chemical substance suppliers for advice when choosing personal protection equipment. Personal protection equipment must comply with the rules in force indicated below.

HANDLING PROTECTION

Protect hands with category III (ref. Directive 89/686/EEC and standard EN 374) work gloves, such as those in PVA, butyl, fluoroelastomer or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to preparations should be checked before use, as it can be unpredictable. Gloves` limit depends on the duration of exposure.

EYE PROTECTION

Wear hood visor or protective visor together with airtight goggles (ref. Standard EN 166).

SKIN PROTECTION

Wear category III professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and Standard EN 344). Wash body with soap and water after removing overalls.

RESPIRATORY PROTECTION

If the threshold value (if available) for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction established by the company’s prevention and protection service is exceeded, wear a mask with an B or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. Standard EN 141).

The use of respiratory tract protection equipment, such as masks like that indicated above, is necessary to reduce worker exposure in the absence of technical measures. The protection provided by masks is in any case limited.

9 Physical & Chemical Properties

9.1 Information on Basic Physical & Chemical Properties

Appearance Liquid
Color Color Palette
Odor Characteristic
Odor Threshold
pH 7 – 8
Melting or Freezing Point
Boiling Point
Distillation Range
Flash Point > 61°C
Evaporation Rate
Flammability of Solids & Gases
Lower Inflammability Limit
Upper Explosive Limit
Lower Explosive Limit
Vapor Pressure
Vapor Density
Specific Gravity 1,100 Kg/l
Solubility Water
Partition Coefficient: Octanol/Water
Ignition Temperature
Decomposition Temperature
Viscosity 1,1200 mPa.s
Reactive Properties

9.2 Other information

VOC (Directive 2004/42/EC) 0.95 g/lt

Matt coatings for interior walls and ceilings. EU limit value for this product
(cat. A / a): 150 g/lt (2007) / 100 g/lt (2010).

10 Stability & Reactivity

10.1 Reactivity

There are no particular risks of reaction with other substances in normal conditions of use.

CALCIUM CARBONATE     Decomposes at temperatures above 800°C.

10.2 | Chemical Stability

The product is stable in normal conditions of use and storage.

10.3 Possibility of Hazardous Reactions

No hazardous reactions are foreseeable in normal conditions of use and storage.

10.4 Conditions to Avoid

None in particular, however the usual precautions used for chemical products should be respected.

10.5 Incompatible Materials

CALCIUM CARBONATE     Acids

10.6 Hazardous Decomposition Products

In the event of thermal decomposition or fire, vapors potentially dangerous to health may be released.

CALCIUM CARBONATE     Calcium Oxides, Carbon Oxides.

11 Toxicological Information

11.1 | Information on Toxicological Effects

This product is corrosive and causes serious burns and vesicles on the skin, which can arise even after exposure. Burns are very stinging and painful. Upon contact with eyes, it may cause serious harm, such as cornea opacity, iris lesions, irreversible eye coloration. Possible vapors are caustic for the respiratory system and may cause pulmonary edema, whose symptoms sometimes arise only after some hours. Exposure symptoms may include: sting, cough, asthma, laryngitis, respiratory disorders, headache, nausea and sickness. If swallowed, it may cause mouth, throat and oesophagus burns, sickness, diarrhoea, edema, larynx swelling and consequently, asphyxia. Perforation of the gastro-intestinal tract is also possible.

CALCIUM HYDROXIDE

  • LD50 (Oral)    6450 mg/kg Rat

TITANIUM DIOXIDE

  • LD50 (Oral)    > 10000 mg/kg Rat

12 Ecological Information

Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation.

12.1 Toxicity

TERBUTRYN

  • LC50 (96h)     1.8 mg/l (Rasbora Heteromorpha)
  • EC50 (48h)     7.1 mg/l (Daphnia Magna)
  • IC50 (72h)     0.0036 mg/l (Selenastrum capricornutum)

12.2 Persistence & Degradability

Information not available.

12.3 Bioaccumulative Potential

Information not available.

12.4 Mobility in Soil

Information not available.

12.5 Results of PBT & vPvB assessment

Information not available.

12.6 Other Adverse Effects

Information not available.

13 Disposal considerations

13.1 Waste Treatment Methods

Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations.

Disposal must be performed through an authorized waste management firm, in compliance with national and local regulations.

CONTAMINATED PACKAGING

Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.

14 Transport Information

The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations.

15 Regulatory Information

15.1 Safety, Health & Environmental Regulations/Legislation Specific for the Substance or Mixture

Seveso Category     None

RESTRICTIONS RELATING TO THE PRODUCT OR CONTAINED SUBSTANCES PURSUANT TO ANNEX XVII TO EC REGULATION 1907/2006.
3

SUBSTANCES IN CANDIDATE LIST (ART. 59 REACH)
None

SUBSTANCES SUBJECT TO AUTHORIZATION (ANNEX XIV REACH)
None

HEALTHCARE CONTROLS
Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers’ health and safety are modest and that the 98/24/EC directive is respected.

15.2 Chemical Safety Assessment

No chemical safety assessment has been processed for the mixture and the substances it contains.

16 Other Information

Text of hazard (H) indications mentioned in section 2 – 3 of the sheet

  • R50/53     Very Toxic To Aquatic Organisms, May Cause Long-Term Adverse Effects In The Aquatic
  • R52/53     Harmful To Aquatic Organisms, May Cause Long-Term Adverse Effects In The Aquatic Environment

GENERAL BIBLIOGRAPHY

  1. Directive 1999/45/EC and following amendments
  2. Directive 67/548/EEC and following amendments and adjustments
  3. Regulation (EC) 1907/2006 (REACH) of the European Parliament
  4. Regulation (EC) 1272/2008 (CLP) of the European Parliament
  5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament
  6. Regulation (EC) 453/2010 of the European Parliament
  7. The Merck Index. – 10th Edition
  8. Handling Chemical Safety
  9. Niosh – Registry of Toxic Effects of Chemical Substances
  10. INRS – Fiche Toxicology (toxicological sheet)
  11. Patty – Industrial Hygiene & Toxicology
  12. N.I. Sax – Dangerous properties of Industrial Materials-7, 1989 Edition

Note For Users

The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability & thoroughness of provided information according to each specific use of the product.

This document must not be regarded as a guarantee on any specific product property.

The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health & safety laws & regulations. The producer is relieved from any liability arising from improper uses.

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